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3M
Marine High Strength Repair Filler PNs 46012, 46013, 46014

Marine High Strength Repair Filler PNs 46012, 46013, 46014

Product catalog summary

Product Identification and Use
3M™ Marine High Strength Repair Filler is identified by product numbers 46012, 46013, and 46014, intended for marine applications. It is produced by 3M's Automotive Aftermarket Division in St. Paul, MN, USA.

Safety and Handling
This product is a flammable solid with health risks such as eye irritation, respiratory issues, and potential carcinogenic effects. Proper handling with protective equipment and ventilation is essential. Store in a ventilated area away from heat and incompatible substances like acids and oxidizing agents.

Hazard Identification
Categorized as a flammable solid (Category 1), with acute toxicity (inhalation, Category 4), and carcinogenicity (Category 1A). Prolonged exposure may damage organs.

First Aid Measures
For inhalation, move to fresh air. For skin contact, wash with soap and water. In case of eye contact, rinse with water for 15 minutes and seek medical attention. If swallowed, rinse mouth and seek medical attention if unwell.

Fire-Fighting Measures
Use dry powder to extinguish fires. Firefighters should wear full protective gear and self-contained breathing apparatus.

Accidental Release Measures
Evacuate area, eliminate ignition sources, and use non-sparking tools for cleanup. Dispose of materials according to regulations.

Composition and Ingredients
Contains inert filler, styrene monomer, vinyl ester resin, and other components, some as trade secrets.

Exposure Controls and Personal Protection
Use ventilation to maintain exposure below limits. If inadequate, use respiratory protection. Recommended PPE includes goggles, gloves, and respirators suitable for organic vapors and particulates.

Physical and Chemical Properties
A gray-brown solid paste with a pungent styrene odor, boiling point of 293°F, and flash point of 88°F. Classified as a flammable solid with specific flammable limits. Insoluble in water with high viscosity.

Stability and Reactivity
Stable under normal conditions but may become unstable at high temperatures or pressure. Avoid heat, sparks, and incompatible materials like strong acids and oxidizing agents.

Toxicological Information
Inhalation can cause respiratory irritation; skin contact may cause mild irritation; eye contact can result in moderate irritation. Prolonged exposure may affect liver, CNS, and auditory functions. Contains carcinogenic chemicals like silica and styrene.

Carcinogenicity
Contains silica and styrene monomer, classified as carcinogenic to humans. Titanium dioxide is possibly carcinogenic when inhaled.

Reproductive Toxicity
Styrene monomer is not classified for reproductive toxicity based on available data.

Specifications
Lists chemical components with CAS numbers, concentrations withheld as trade secrets.

First Aid Measures
Similar to previous section, emphasizing medical attention if symptoms develop.

Fire-Fighting Measures
Use water or foam for extinguishing. Closed containers may explode under heat.

Accidental Release Measures
Evacuate area, eliminate ignition sources, ventilate, and use absorbent materials for cleanup.

Handling and Storage
Avoid confined spaces, heat, and ignition sources. Store in original containers away from sunlight and incompatible materials.

Exposure Controls/Personal Protection
Use adequate ventilation and PPE such as goggles, gloves, and respirators. Follow exposure limits for components.

Physical and Chemical Properties
Red, viscous solid with slight ester odor, flash point of 111 ºC, negligible water solubility.

Stability and Reactivity
Stable under normal conditions but may react with certain agents. Avoid heat and incompatible materials.

Toxicological Information
May cause respiratory irritation, skin reactions, and severe eye irritation. Acute toxicity data indicates low toxicity levels.

Reproductive Toxicity
Benzoyl Peroxide not classified for reproductive effects; Oxirane, Polymer with Methyloxirane, Monobutyl Ether shows no classification for male reproduction.

Specific Target Organ Toxicity
Various organ systems affected by Oxirane, Polymer with Methyloxirane, Monobutyl Ether through inhalation and ingestion.

Aspiration Hazard
Data insufficient for classification.

Ecological Information
Contact manufacturer for additional ecotoxicological and chemical fate information.

Disposal Considerations
Dispose according to regulations. Incineration in a permitted facility is an alternative.

Transport Information
Visit 3M website or contact listed phone numbers for transport details.

Regulatory Information
Complies with US Federal and State regulations, including TSCA. Benzoyl Peroxide subject to EPCRA reporting.

Other Information
NFPA and HMIS hazard classifications indicate moderate health and flammability risks. Disclaimer included regarding information accuracy.

Catalog excerpts

Marine High Strength Repair Filler PNs 46012, 46013, 46014-1

Marine High Strength Repair Filler PNs 46012, 46013, 46014 Safety Data Sheet Copyright,2020, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: Issue Date: Version Number: Supercedes Date: Product identifier 3M™ Marine High Strength Repair Filler PNs 46012, 46013, 46014 ID Number(s): 60-9800-2720-9, 60-9800-2721-7, 60-9800-2722-5 7100036757, 7000120452, 7000000605 Recommended use Marine Filler, Marine Supplier's details MANUFACTURER: DIVISION: ADDRESS: Telephone: 3M Center, St. Paul, MN 55144-1000, USA 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 07-4142-1, 29-5993-0 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. ________________________________________________________________________________________________________ Page 1 of

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Marine High Strength Repair Filler PNs 46012, 46013, 46014

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3M™ Marine High Strength Repair Filler PN 46010 (6 fl. oz.); 46012 (pint); 46013 (quart); 46014 (gallon), Safety Data Sheet Copyright,2019,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: Issue Date: Version Number: Supercedes Date: SECTION 1: Identification...

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Marine High Strength Repair Filler PNs 46012, 46013, 46014-4

3M™ Marine High Strength Repair Filler PN 46010 (6 fl. oz.); 46012 (pint); 46013 (quart); 46014 (gallon), 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Hazard Statements Flammable solid. Causes eye irritation. Harmful if inhaled. May cause drowsiness or dizziness. May cause cancer. Causes damage to organs: liver | sensory organs | Causes damage to organs through prolonged or repeated exposure: respiratory system | sensory organs | May cause damage to organs through prolonged or repeated exposure: liver | Precautionary Statements General: Keep out of reach of children....

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Marine High Strength Repair Filler PNs 46012, 46013, 46014-5

3M™ Marine High Strength Repair Filler PN 46010 (6 fl. oz.); 46012 (pint); 46013 (quart); 46014 (gallon), IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for metal fires such as dry powder to extinguish. Storage: Store in a well-ventilated place. Store locked up. Keep container tightly closed. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 34% of the mixture consists of ingredients of unknown acute oral toxicity. 34% of the mixture consists of ingredients of unknown...

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Marine High Strength Repair Filler PNs 46012, 46013, 46014-6

3M™ Marine High Strength Repair Filler PN 46010 (6 fl. oz.); 46012 (pint); 46013 (quart); 46014 (gallon), 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for metal fires such as dry powder to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Hydrocarbons Carbon monoxide Carbon dioxide Toxic Vapor, Gas, Particulate Condition During...

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Marine High Strength Repair Filler PNs 46012, 46013, 46014-7

3M™ Marine High Strength Repair Filler PN 46010 (6 fl. oz.); 46012 (pint); 46013 (quart); 46014 (gallon), of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed to prevent loss of stabilizing materials. heat. Store...

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Marine High Strength Repair Filler PNs 46012, 46013, 46014-8

3M™ Marine High Strength Repair Filler PN 46010 (6 fl. oz.); 46012 (pint); 46013 (quart); 46014 (gallon), particles/cu. ft.(5 mg/m3);TWA(respirable fraction):5 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust...

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